The 21-year-old was behind the wheel of a silver Vauxhall Corsa which was involved in collision with a Stagecoach East Midlands bus on Southgate, Eckington, at around 7.40am on Wednesday.
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Officers are keen to hear from anyone with dashcam footage showing the two vehicles in the area immediately before the incident.
Call 101 and quote 19*168524 and the officer in the case, DC Richard Howiss.